Tuesday, May 17, 2022

A way to overcome the scaling up problems of perovskites

A solution to perovskite solar cell scalability problems.

Despite perovskite solar cells’ amazing improvements in power conversion efficiency, scaling out from individual small-area devices to large-area modules while maintaining commercial competitiveness compared to other thin-film solar cells remains difficult. Major obstacles include the reduction of both the resistive losses and intrinsic defects in the electron transport layers and the reliable fabrication of high-quality large-area perovskite films.

In a new study, scientists led by Mohammad Nazeeruddin at EPFL have found a way to overcome the scaling-up problems of perovskites. They came up with an easy solvothermal method that can produce single-crystalline titanium dioxide rhombohedral nanoparticles that can be used to build a perovskite film.

The new structure has fewer “lattice” mismatches, referring to the titanium dioxide nanoparticles’ “ladder-like” shape. This equates fewer flaws, which provides smoother electron flow and lower power loss throughout the device.

When scientists tested their new nanoparticle-based, small-size solar cells, they achieved power-conversion efficiency of 24.05% and a fill factor of 84.7%.

The scientists also fabricated large-area cells, which certified efficiency of 22.72% with an active area of nearly 24 cm2.

Scientists noted“This represents the highest efficiency modules with the lowest loss in efficiency when scaling up.”

Journal Reference:

  1. Ding, Y., Ding, B., Kanda, H. et al. single-crystalline TiO2 nanoparticles for stable and efficient perovskite modules. DOI: 10.1038/s41565-022-01108-1

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